The kit you referenced would work, but you do need to have the performance valve springs and retainers. The Full Kit has all the stuff in the "SK" (i.e. "Small Kit") and also includes performance springs, retainers, keepers, and valve stem seals. Here's the link at the Comp Cams website:
High Energy 206/206 Hydraulic Flat Cam K-Kit for Chevrolet 173-207/2.8-3.4L V6. Good power for 2 or 4 wheel drive S-10, S-15 or blazer. Works well in mild towing applications. Smooth idle.
www.compcams.com
They say "temporarily out of stock" but you could piece-out the kit or just wait until back in stock. Summit Racing also carries Comp Cams parts:
https://www.summitracing.com/parts/cca-k16-232-4
Same price as the Comp Cams website, and they're showing a ship date of Feb 6, 2023. The pic at their web **** shows exactly what parts are in the kit.
The valve springs have to be upgraded, because the stock springs will coil-bind when used with the higher-lift cam. Note that early Z28 valve springs and keepers are also compatible with the cam kit, so you might be able to source them separately. These springs require specific retainers.
Summit has the Comp Cam springs for the V6 available to ship now:
https://www.summitracing.com/parts/CCA-980-12
They also have the retainers available separately:
https://www.summitracing.com/parts/cca-742-12
Rather expensive, you may find generic LT1 parts cheaper, IDK.
The valve keepers would just be stock items you could buy at Summit, Rockauto, eBay, etc.
If you're going to get the block hot-tanked, the caustic solution will eat up the cam bearings. So you gotta get new ones anyway. IIRC machine shop quoted $40 for those, that's quite reasonable if that includes installation. I'd leave that bearing R&R to the pro's, BTW.
Cool you have access to a ball hone, it doesn't take much to put a decent cross-hatch in the cylinders with one of those. I find Marvel Mystery Oil makes a great lube for honing and it smells great, anyway. If you do the deglazing after you get the block back, be sure to Scrub Scrub Scrub the cylinder bores with Hot water and a bristle brush (a round toilet bowl brush works great) until a white paper towel sprayed with WD comes back clean when you wipe down the cylinders. Otherwise the abrasive works into the x-hatches and causes extreme wear to the rings. Remember, Hot, Soapy water, that's the trick. I like Dawn but whatever your preference.
For rocker arms, you can get a nice bump in performance by using Comp Cams 1.6:1 roller-tipped Magnum rocker arms. The stock rocker ratio is 1.52 and the 1.6:1 ratio increases lift slightly and also a bit of duration as a result of the increased lift.
Rather expensive at $170.95, you may find generic LT1 parts cheaper, IDK. These have gone up about $100 in 20 years but what can ya do, inflation is rampant! IHMO still worth the $$$.
The roller tips reduce friction on the valve stems, and hence lessen valve guide wear, reduce oil temps and give more HP. With the use of performance valve springs, the added lift should work just fine with the 252 cam. I've gotten away with using them in my rigs without changing the valve springs, but combined with the cam you do need the performance springs.
Note that any generic Small Block Chevy V8 Non-Self-Aligning roller-tipped rocker arm will also work. I've been running a set of cheap eBay V8 rockers in my 3.4 for over 20 years and they seem to work just as well as the Magnums I used in my old 2.8 Trooper. But the Magnums are very high-quality pieces, you can tell when you look at them. Of course even the "cheap" V8 items aren't probably too cheap on eBay anymore.
Note, if you use V8 rockers you have to use the V6 rocker balls. V6 heads use a 10mm rocker stud; the V8 rocker studs are typically 3/8" or larger. But the body of the non-self-aligning rocker is identical.
Here's a generic set of V8 rockers on eBay for around $107 shipped, that looks decent:
Find many great new & used options and get the best deals for Chevy SBC 350 1.6 Ratio 3/8" Steel Roller Tip Rocker Arms Set (w/Nuts and Balls) at the best online prices at eBay! Free shipping for many products!
www.ebay.com
You'd have to use V6 rocker balls and also V6 locknuts on these. Just get generic V6 items, I looked up the rocker balls at Rockauto and they're .92 each plus ship. New nuts, if you need 'em, as cheap as .62 each.
Anyway, there's a few options for ya, HTH & Merry Christmas!..............ed
p.s. No Worries about questions, that's the purpose of this forum!! 😺